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The researchers, led by the University of Cambridge, are developing low-cost light-harvesting semiconductors that power devices for converting water into clean hydrogen fuel, using just the power of the sun. These semiconducting materials, known as copper oxides, are cheap, abundant and non-toxic, but their performance does not come close to silicon, which dominates the semiconductor market.

However, the researchers found that by growing the copper oxide crystals in a specific orientation so that electric charges move through the crystals at a diagonal, the charges move much faster and further, greatly improving performance. Tests of a copper oxide light harvester, or photocathode, based on this fabrication technique showed a 70% improvement over existing state-of-the-art oxide photocathodes, while also showing greatly improved stability.

The researchers say their results, reported in the journal Nature, show how low-cost materials could be fine-tuned to power the transition away from fossil fuels and toward clean, sustainable fuels that can be stored and used with existing energy infrastructure.

Copper (I) oxide, or cuprous oxide, has been touted as a cheap potential replacement for silicon for years, since it is reasonably effective at capturing sunlight and converting it into electric charge. However, much of that charge tends to get lost, limiting the material’s performance.

“Like other oxide semiconductors, cuprous oxide has its intrinsic challenges,” said co-first author Dr Linfeng Pan from Cambridge’s Department of Chemical Engineering and Biotechnology. “One of those challenges is the mismatch between how deep light is absorbed and how far the charges travel within the material, so most of the oxide below the top layer of material is essentially dead space.”

“For most solar cell materials, it’s defects on the surface of the material that cause a reduction in performance, but with these oxide materials, it’s the other way round: the surface is largely fine, but something about the bulk leads to losses,” said Professor Sam Stranks, who led the research. “This means the way the crystals are grown is vital to their performance.”

To develop cuprous oxides to the point where they can be a credible contender to established photovoltaic materials, they need to be optimised so they can efficiently generate and move electric charges – made of an electron and a positively-charged electron ‘hole’ – when sunlight hits them.

One potential optimisation approach is single-crystal thin films – very thin slices of material with a highly-ordered crystal structure, which are often used in electronics. However, making these films is normally a complex and time-consuming process.

Using thin film deposition techniques, the researchers were able to grow high-quality cuprous oxide films at ambient pressure and room temperature. By precisely controlling growth and flow rates in the chamber, they were able to ‘shift’ the crystals into a particular orientation. Then, using high temporal resolution spectroscopic techniques, they were able to observe how the orientation of the crystals affected how efficiently electric charges moved through the material.

“These crystals are basically cubes, and we found that when the electrons move through the cube at a body diagonal, rather than along the face or edge of the cube, they move an order of magnitude further,” said Pan. “The further the electrons move, the better the performance.”

“Something about that diagonal direction in these materials is magic,” said Stranks. “We need to carry out further work to fully understand why and optimise it further, but it has so far resulted in a huge jump in performance.” Tests of a cuprous oxide photocathode made using this technique showed an increase in performance of more than 70% over existing state-of-the-art electrodeposited oxide photocathodes.

“In addition to the improved performance, we found that the orientation makes the films much more stable, but factors beyond the bulk properties may be at play,” said Pan.

The researchers say that much more research and development is still needed, but this and related families of materials could have a vital role in the energy transition.

“There’s still a long way to go, but we’re on an exciting trajectory,” said Stranks. “There’s a lot of interesting science to come from these materials, and it’s interesting for me to connect the physics of these materials with their growth, how they form, and ultimately how they perform.”

The research was a collaboration with École Polytechnique Fédérale de Lausanne, Nankai University and Uppsala University. The research was supported in part by the European Research Council, the Swiss National Science Foundation, and the Engineering and Physical Sciences Research Council (EPSRC), part of UK Research and Innovation (UKRI). Sam Stranks is Professor of Optoelectronics in the Department of Chemical Engineering and Biotechnology, and a Fellow of Clare College, Cambridge.

 

Reference:
Linfeng Pan, Linjie Dai et al. ‘High carrier mobility along the [111] orientation in Cu2O photoelectrodes.’ Nature (2024). DOI: 10.1038/s41586-024-07273-8

For more information on energy-related research in Cambridge, please visit the Energy IRC, which brings together Cambridge’s research knowledge and expertise, in collaboration with global partners, to create solutions for a sustainable and resilient energy landscape for generations to come. 

Researchers have found a way to super-charge the ‘engine’ of sustainable fuel generation – by giving the materials a little twist.

orange via Getty ImagesAbstract orange swirls

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Using the James Webb Space Telescope, an international team of astronomers led by the University of Cambridge have spotted a ‘dead’ galaxy when the universe was just 700 million years old, the oldest such galaxy ever observed.

This galaxy appears to have lived fast and died young: star formation happened quickly and stopped almost as quickly, which is unexpected for so early in the universe’s evolution. However, it is unclear whether this galaxy’s ‘quenched’ state is temporary or permanent, and what caused it to stop forming new stars.

The results, reported in the journal Nature, could be important to help astronomers understand how and why galaxies stop forming new stars, and whether the factors affecting star formation have changed over billions of years.

“The first few hundred million years of the universe was a very active phase, with lots of gas clouds collapsing to form new stars,” said Tobias Looser from the Kavli Institute for Cosmology, the paper’s first author. “Galaxies need a rich supply of gas to form new stars, and the early universe was like an all-you-can-eat buffet.”

“It’s only later in the universe that we start to see galaxies stop forming stars, whether that’s due to a black hole or something else,” said co-author Dr Francesco D’Eugenio, also from the Kavli Institute for Cosmology.

Astronomers believe that star formation can be slowed or stopped by different factors, all of which will starve a galaxy of the gas it needs to form new stars. Internal factors, such as a supermassive black hole or feedback from star formation, can push gas out of the galaxy, causing star formation to stop rapidly. Alternatively, gas can be consumed very quickly by star formation, without being promptly replenished by fresh gas from the surroundings of the galaxy, resulting in galaxy starvation.

“We’re not sure if any of those scenarios can explain what we’ve now seen with Webb,” said co-author Professor Roberto Maiolino. “Until now, to understand the early universe, we’ve used models based on the modern universe. But now that we can see so much further back in time, and observe that the star formation was quenched so rapidly in this galaxy, models based on the modern universe may need to be revisited.”

Using data from JADES (JWST Advanced Deep Extragalactic Survey), the astronomers determined that this galaxy experienced a short and intense period of star formation over a period between 30 and 90 million years. But between 10 and 20 million years before the point in time where it was observed with Webb, star formation suddenly stopped.

“Everything seems to happen faster and more dramatically in the early universe, and that might include galaxies moving from a star-forming phase to dormant or quenched,” said Looser.

Astronomers have previously observed dead galaxies in the early universe, but this galaxy is the oldest yet – just 700 million years after the big bang, more than 13 billion years ago. This observation is one of the deepest yet made with Webb.

In addition to the oldest, this galaxy is also relatively low mass – about the same as the Small Magellanic Cloud (SMC), a dwarf galaxy near the Milky Way, although the SMC is still forming new stars. Other quenched galaxies in the early universe have been far more massive, but Webb’s improved sensitivity allows smaller and fainter galaxies to be observed and analysed.

The astronomers say that although it appears dead at the time of observation, it’s possible that in the roughly 13 billion years since, this galaxy may have come back to life and started forming new stars again.

“We’re looking for other galaxies like this one in the early universe, which will help us place some constraints on how and why galaxies stop forming new stars,” said D’Eugenio. “It could be the case that galaxies in the early universe ‘die’ and then burst back to life – we’ll need more observations to help us figure that out.”

The research was supported in part by the European Research Council, the Royal Society, and the Science and Technology Facilities Council (STFC), part of UK Research and Innovation (UKRI).

 

Reference:
Tobias J. Looser et al. ‘A recently quenched galaxy 700 million years after the Big Bang.’ Nature (2024). DOI: 10.1038/s41586-024-07227-0

A galaxy that suddenly stopped forming new stars more than 13 billion years ago has been observed by astronomers.

JADES CollaborationFalse-colour JWST image of a small fraction of the GOODS South field, with JADES-GS-z7-01-QU highlighted

The text in this work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License. Images, including our videos, are Copyright ©University of Cambridge and licensors/contributors as identified. All rights reserved. We make our image and video content available in a number of ways – on our main website under its Terms and conditions, and on a range of channels including social media that permit your use and sharing of our content under their respective Terms.

YesLicence type: Public Domain